There are two ways to Set the default page of the website In IIS 7.0
1. Directly on the IIS 7.0 Manager
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1. Open IIS Manager
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2. Select your web site directory
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3. Make sure Feature View is selected
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4. On center page, under HTTP Feature select Default Document
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5. Type the Default Page you want.
2. By using Web.Config file, just add to following line to your web.config file
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<configuration>
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<system.webServer>
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<defaultDocument>
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<files>
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<add value="index.php" />
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</files>
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</defaultDocument>
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</system.webServer>
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</configuration>
Other Resources:
NetOMatrix | IIS Net